The composition of zircon in Variscan granites from Northern Portugal

Authors

  • H. C.B. Martins Geology Centre. Department of Geosciences Environment and Spatial Planning. Faculty of Sciences, Porto University
  • J. Abreu Geology Centre. Department of Geosciences Environment and Spatial Planning. Faculty of Sciences, Porto University

DOI:

https://doi.org/10.3989/egeol.41729.318

Keywords:

zircon composition, trace elements, Variscan granites

Abstract


A group of slightly peraluminous Variscan plutons in Northern Portugal were selected from the study of zircon composition. The selected plutons are: the Vila Pouca de Aguiar and the Lavadores-Madalena plutons with I-type affinities and the Vieira do Minho pluton, an l-S transitional type. Zircon occurs as euhedral to subhedral crystals and exhibit finely concentric oscillatory magmatic zoning mainly related to variations of Hf, Y, U and Th concentrations. Most zircon crystals show the dominant “xenotime” substitution. The zircon crystals have Zr/Hf ratio in the range of 21 to 52, with no significant differences between the different granites. These values are in the same range of other peraluminous granites and are in accordance with a crustal signature of zircon. Moreover, the range of Zr/Hf values in zircon crystals overlaps with that of crustal sources and consequently to the potential protoliths proposed in the genesis of the Vieira do Minho and the Vila Pouca de Aguiar plutons, namely meta-igneous crustal sources at different levels. Although zircon from the Lavadores-Madalena pluton has a compositional range similar to the other plutons, an origin by hibridisation has been proposed. However, similar zircon chemistry between this pluton and Vila Pouca de Aguiar and Vieira do Minho plutons could also suggest a similar crustal source.

Downloads

Download data is not yet available.

References

Abreu, J. (2012). Estudo geoquímico de zircão de granitos do NW Português. Master Thesis, Universidade do Porto, 176 pp.

Almeida, A.; Martins, H.C.B. & Noronha, F. (2002). Hercynian acid magmatism and related mineralisations in Northern Portugal. Gondwana Research, 5: 423–434. http://dx.doi.org/10.1016/S1342-937X(05)70733-4

Bea, F. (1996). Residence of REE, Y, Th and U in Granites and Crustal Protoliths; Implications for the Chemistry of Crustal Melts. Journal of Petrology, 37: 521–552. http://dx.doi.org/10.1093/petrology/37.3.521

Bea, F.; Montero, P. & Ortega, M. (2006). A LA-ICPMS evaluation of Zr reservoirs in common crustal rocks: implications for Zr and Hf geochemistry and zircon-forming processes. Canadian Mineralogist, 44: 693–714. http://dx.doi.org/10.2113/gscanmin.44.3.693

Belousova, E.A.; Griffin, W.L.; O'Reilly, S.Y. & Fisher, N.I. (2002). Igneous zircon: trace element composition as an indicator of source rock type. Contributions to Mineralogy and Petrology, 143: 602–622. http://dx.doi.org/10.1007/s00410-002-0364-7

Belousova, E.A.; Griffin, W.L. & O'Reilly, S.Y. (2006). Zircon crystal morphology, trace element signatures and Hf isotope composition as a tool for petrogenetic modelling: examples from Eastern Australian granitoids. Journal of Petrology, 47: 329–353. http://dx.doi.org/10.1093/petrology/egi077

Benisek, A. & Finger, F. (1993). Factors controlling the development of prism faces in granite zircons: a microprobe study. Contributions to Mineralogy and Petrology, 114: 441–451. http://dx.doi.org/10.1007/BF00321749

Cerny, P.; Meintzer, R.E. & Anderson, A.J. (1985). Extreme fractionation in rare-element granitic pegmatites: selected examples of data and mechanisms. Canadian Mineralogist, 23: 381–421.

Claiborne, L.L.; Miller, C.F.; Walker, B A.; Wooden, J.L.; Mazdab, F.K. & Bea, F. (2006). Tracking magmatic processes through Zr/Hf ratios in rocks and Hf and Ti zoning in zircons: An example from the Spirit Mountain batholith, Nevada. Mineralogical Magazine, 70: 517–543. http://dx.doi.org/10.1180/0026461067050348

Claiborne L.L.; Miller C.F. & Wooden J.L. (2010). Trace element composition of igneous zircon: A thermal and compositional record of the accumulation and evolution of a large silicic batholith, Spirit Mountain, Nevada. Contributions to Mineralogy and Petrology, 160: 511–31. http://dx.doi.org/10.1007/s00410-010-0491-5

Dias, G.; Simões, P.P.; Ferreira, N. & Leterrier, J. (2002). Mantle and crustal sources in the genesis of late-Hercynian granitoids (NW Portugal): geochemical and Sr-Nd isotopic constraints. Gondwana Research, 5: 287–305. http://dx.doi.org/10.1016/S1342-937X(05)70724-3

Ferreira, N.; Iglésias, M.; Noronha, F.; Pereira, E.; Ribeiro, A. & Ribeiro, M.L. (1987). Granitos da Zona Centro Ibérica e seu enquadramento geodinâmico. In: Geología de los Granitoides y Rocas Asociadas del Macizo Hesperico (Bea, F.; Carnicero, A.; Gonzalo, J.; López Plaza, M. & Rodríguez Alonso M., Eds), Editorial Rueda, Madrid, 37–51.

Gagnevin, D.; Daly, J.S. & Kronz, A., (2010). Zircon texture and chemical composition as a guide to magmatic processes and mixing in a granitic environment and coeval volcanic system. Contributions to Mineralogy and Petrology, 159: 579–596. http://dx.doi.org/10.1007/s00410-009-0443-0

Hanchar, J.M. & Miller, C.F. (1993). Zircon zonation patterns as revealed by cathodoluminescence and backscattered electron images: implications for interpretation of complex crustal histories. Chemical Geology, 110: 1–13. http://dx.doi.org/10.1016/0009-2541(93)90244-D

Heaman, L.M.; Bowins, R. & Crocket, J. (1990). The chemical composition of igneous zircon suites: implications for geochemical tracer studies. Geochimica et Cosmochimica Acta, 54: 1597–1607. http://dx.doi.org/10.1016/0016-7037(90)90394-Z

Hoskin, P.W.O.; Kinny, P.D.; Wyborn, D. & Chappell, B.W. (2000). Identifying accessory mineral saturation during differentiation in granitoid magmas: an integrated approach. Journal of Petrology, 41: 1365–1369. http://dx.doi.org/10.1093/petrology/41.9.1365

Hoskin, P. & Schaltegger U. (2003). The composition of zircon and igneous and metamorphic petrogenesis. Reviews in Mineralogy and Geochemistry, 53: 27–62. http://dx.doi.org/10.2113/0530027

Martins, H.C.B.; Sant'Ovaia, H. & Noronha, F. (2007). Post-tectonic granite intrusion controlled by a deep Variscan fault in Northern Portugal. Cadernos do Laboratorio Xeolóxico de Laxe, 32: 221–235.

Martins, H.C.B.; Sant'Ovaia, H. & Noronha, F. (2009). Genesis and emplacement of felsic Variscan plutons within a deep crustal lineation, the Penacova-Régua-Verín fault: an integrated geophysics and geochemical study (NW Iberian Peninsula). Lithos, 111: 142–155. http://dx.doi.org/10.1016/j.lithos.2008.10.018

Martins, H.C.B.; Sant'Ovaia, H.; Abreu, J.; Oliveira, M. & Noronha, F. (2011). Emplacement of the Lavadores granite (NW Portugal): U/Pb and AMS results. Comptes Rendus Geoscience, 343: 387–396. http://dx.doi.org/10.1016/j.crte.2011.05.002

Martins, H.C.B.; Sant'Ovaia, H. & Noronha, F. (2013). Late-Variscan emplacement and genesis of the Vieira do Minho composite pluton, Central Iberian Zone: constraints from U-Pb zircon geochronology, AMS data and Sr-Nd-O isotope geochemistry. Lithos, 162–163: 221–235. http://dx.doi.org/10.1016/j.lithos.2013.01.001

Martins, H.C.B.; Simões, P.P. & Abreu, J. (2014). Zircon crystal morphology and internal structures as a tool for constraining magma sources: Examples from northern Portugal Variscan biotite-rich granite plutons. Comptes Rendus Geoscience, 346: 233-243. http://dx.doi.org/10.1016/j.crte.2014.07.004

Pérez-Soba, C.; Villaseca, C.; González del Tánago, J. & Nasdala, L. (2007). The composition of zircon in the peraluminous Hercynian granites of the Spanish Central System batholith. The Canadian Mineralogist, 4: 509–527. http://dx.doi.org/10.2113/gscanmin.45.3.509

Pupin, J.P. (2000). Granite genesis related to geodynamics from Hf-Y in zircon. Transaction of the Royal Society of Edinburg: Earth Sciences, 91: 254–256. http://dx.doi.org/10.1017/S0263593300007410

Silva, M.M.V.G. (1995). Mineralogia, petrologia, e geoquímica de encraves de rochas graníticas de algumas regiões Portuguesas. PhD thesis, Coimbra University. Portugal, 288 pp.

Silva, M.M.V.G. & Neiva, A.M. (1998). Geoquímica de encraves microgranulares e granitos hospedeiros da região de Vila Nova de Gaia, Norte de Portugal. Comunicações do Instituto Geológico e Mineiro, 84: 35–38.

Silva, M.M.V.G. (2010). O granito de Lavadores e os seus encraves. In: Ciências Geológicas – Ensino e Investigação e sua História (Cotelo Neiva, J.M.; Ribeiro, A.; Mendes Victor, L.; Noronha, F. & Magalhães Ramalho, M., Eds), 1: 269–279.

Smith, D.G.W.; de St. Jorre, L.; Reed, S.J.B. & Long, J.V.P. (1991). Zonally metamictized and other zircons from Thor Lake, Northwest Territories. The Canadian Mineralogist, 29: 301–309.

Speer, J.A. (1980). Zircon. In Orthosilicates (Ribbe, P.H. Ed). Reviews in Mineralogy, 5: 67–112.

Watson, E.B. (1996). Dissolution, growth and survival of zircons during crustal fusion: kinetic principles, geological models and implications for isotopic inheritance. Transaction of the Royal Society of Edinburg: Earth Sciences, 87: 43–56. http://dx.doi.org/10.1017/S0263593300006465

Watson, E.B. & Cherniak D.J. (1997). Oxygen diffusion in zircon. Earth and Planetary Science Letters, 148: 527–544. http://dx.doi.org/10.1016/S0012-821X(97)00057-5

Watson, E.B., Wark, D.A. & Thomas, J.B. (2006). Crystallisation thermometers for zircon and rutile. Contributions to Mineralogy and Petrology, 151: 413–433. http://dx.doi.org/10.1007/s00410-006-0068-5

Published

2014-12-30

How to Cite

Martins, H. C., & Abreu, J. (2014). The composition of zircon in Variscan granites from Northern Portugal. Estudios Geológicos, 70(2), e018. https://doi.org/10.3989/egeol.41729.318

Issue

Section

Articles