Main characteristics and genesis of the Vale de Pães skarn (Cuba-Vidigueira, Ossa Morena Zone, Portugal)
DOI:
https://doi.org/10.3989/egeol.40150.101Keywords:
Magnetite-sulphide mineralisation, Fe(Mg/Ca) Skarn, Chemical zoning, Ossa Morena ZoneAbstract
The Vale de Pães (Cuba-Vidigueira) mineralisation is composed of magnetite ± sulphides and hosted in a Pre-Variscan metamorphic sequence intruded by igneous rocks belonging to the Beja Igneous Complex. Its mineral and chemical features are compatible with a zoned Fe-skarn: Mg-rich (Fo + Di90, oxidised) and Ca-rich (Grs + Di81-39, oxidised or relatively reduced). In the Fe-Mg skarn, magnetite deposition occurred along with the anhydrous mineral assemblage at ≈ 600 °C; sulphides precipitated from the retrograde stage onset (≤ 550 °C) and during the hydrated and carbonate phases formation period (< 420 °C). In the Fe-Ca skarn, magnetite precipitated during the retrograde stage (< 550 °C) together with the hydrated mineral association, and was followed by sulphides at ≈ 400°C. The mineralising process involved moderate-high salinity fluids and was controlled by variations in redox potential and pH.
Downloads
References
Aleksandrov, S.M. (1998). Geochemistry of Skarn and Ore Formation in Dolomites. VSP, Utrecht, Tokyo, 300 pp.
Boynton, W.V. (1984). Geochemistry of the rare earth elements: meteorite studies. In: Rare earth element geochemistry (Henderson, P., ed.). Elsevier, Amsterdam, 63-114.
Carvalho, D. (1976). Les gisements de fer du Portugal. In: The iron ore deposits of Europe and adjacent areas (Zitzmann, A., ed.), Commission for the Geological Map of the World. Subcommission for the Metallogenic Map of the World, Hannover, 255-260.
Carvalho, D. & Oliveira, V. (1992). Recursos minerais. In: Notícia Explicativa da Folha 8: Carta Geológica de Portugal na escala 1:200 000. Serviços Geológicos de Portugal, 81-83.
Degens, E.T.; Wiliams, E.G. & Keith, E.G. (1958). Application of geochemical criteria [Pennsilvania], part 2 of environmental studies of carboniferous sediments. American Association of Petroleum Geologists Bulletin, 42: 981-997.
Einaudi, M.T. & Burt, D.M. (1982). Introduction - terminology, classification, and composition of skarn deposits. Economic Geology, 77: 745-754. doi:10.2113/gsecongeo.77.4.745
Einaudi, M.T.; Meinert, L.D. & Newberry, R.J. (1981). Skarn deposits. Economic Geology, 75th Anniversary Volume: 317-391.
Gromet L.P.; Dymek, R.F.; Haskin L.A. & Korotev, R.L. (1984). The “North American shale composite”: its compilation, major and trace element characteristics. Geochimica et Cosmochimica Acta, 48: 2469-2482. doi:10.1016/0016-7037(84)90298-9
Meinert, L.D. (1992). Skarns and skarn deposits. Geoscience Canada, 10: 145-162.
Meinert, L.D. (1997). Application of skarn deposit zonation models to mineral exploration. Exploration and Mining Geology, 6: 185-208.
Michard, A. & Albarède, F. (1986). The REE content of some hydrothermal fluids. Chemical Geology, 55: 51-60. doi:10.1016/0009-2541(86)90127-0
Oliveira, V. (1986). Prospecção de minérios metálicos a sul do Tejo. Geociências - Revista da Universidade de Aveiro, 1: 15-22.
Piçarra, J.; Oliveira, V. & Oliveira, T. (1992). Paleozóico. In: Notícia Explicativa da Folha 8, Carta Geológica de Portugal, escala 1:200000, Lisboa, Serviços Geológicos de Portugal, 25-30.
Pons, J.M.; Franchini, M.; Meinert, L.; Recio, C. & Etcheverry, R. (2009). Iron Skarns of the Vegas Peladas District, Mendoza, Argentina. Economic Geology, 104: 157-184. doi:10.2113/gsecongeo.104.2.157
Purtov, V.K.; Kholodnov, V.V.; Afilogov, V.N. & Nechkin, G.S. (1989). The role of chlorine in the formation of magnetite skarns. International Geology Review, 31: 63-71. doi:10.1080/00206818909465861
Salgueiro, R.M.M. (in prep.). Caracterização e génese das mineralizações de magnetite - sulfuretos de Monges (Santiago do Escoural, Montemor-o-Novo) e ensaio comparativo com as suas congéneres em Orada e Vale de Pães (Serpa - Vidigueira). Tese de Doutoramento (PhD Thesis), Universidade de Lisboa, Lisboa.
Serviço de Fomento Mineiro (1968). Descrição da sondagem, n.º 42 de Vale de Pães. Serviço de Fomento Mineiro, Relatório Interno, Beja.
Serviço de Fomento Mineiro, 1980 (aprox.), Cartas Geológicas na escala 1:25000, n.º 499 (Cuba) e n.º 510 (S. Matias). Serviço de Fomento Mineiro, Beja.
Turekian, K.K. & Wedepohl, K.H. (1961). Distribution of the elements in some major units of Earth’s crust. Geological Society of American Bulletin, 72: 175-192. doi:10.1130/0016-7606(1961)72[175:DOTEIS]2.0.CO;2
Wedepohl, K.H. (1974). Handbook of Geochemistry. Springer-Verlag, Berlin, 374 pp.
Wilde, P; Quinby-Hunt, M.S. & Erdtmann, B.D. (1996). The whole-rock cerium anomaly: a potential indicator of eustatic sea-level changes in shales of the potential indicator of eustatic sea-level changes in shales of anoxic facies. Sedimentary Geology, 101: 43-53. doi:10.1016/0037-0738(95)00020-8
Zharikov, V.A. (1970). Skarns. International Geology Review, 12: 541-559, 619-647, 760-775. doi:10.1080/00206817009475262
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2010 Consejo Superior de Investigaciones Científicas (CSIC)

This work is licensed under a Creative Commons Attribution 4.0 International License.
© CSIC. Manuscripts published in both the print and online versions of this journal are the property of the Consejo Superior de Investigaciones Científicas, and quoting this source is a requirement for any partial or full reproduction.
All contents of this electronic edition, except where otherwise noted, are distributed under a Creative Commons Attribution 4.0 International (CC BY 4.0) licence. You may read the basic information and the legal text of the licence. The indication of the CC BY 4.0 licence must be expressly stated in this way when necessary.
Self-archiving in repositories, personal webpages or similar, of any version other than the final version of the work produced by the publisher, is not allowed.







