Hidrogeoquímica de los manantiales sulfhídricos y ferruginosos de las facies Purbeck-Weald del noroeste de la Cordillera Iberica (provincia de Soria)

Abstract

The goal of this article is to study the chemical composition of the sulfide-bearingand iron-rich springs in Soria. These springs are mainly located on sedimentary rocks of the Purbeck-Weald facies and most precisely in the Oncala group materials. Sulfide-bearing spring water belongs to calcium sulfate facies. It pH is basic or neutral. This kind of springs is mainly in the eastern area of Oncala group. Sulfate reduction with presence of organic matter seems to be the most common ORIGIN of the H₂S. lronrich springs are more often located in the westside of Oncala group. Water of these springs has calcium bicarbonate character, very low salinity and acid pH. These differences on major ion chemical composition likely show the influence of the lithologic and mineralogic changes in the Oncala group. It presents low soluble terrigenous sediments in the western area whereas eastward there is a facies lateral change with the appearance of carbonates and sulfates. On the other hand, none of the iron-rich springs contains H₂S and coversely Fe is never detected in the sulfide-bearing springs, although sometimes they appear together. This fact is in accordance with the plot of the two water types have in the pH/Eh diagrams.